In 1936 it was the widely accepted view that the internal rotation of methyl groups within a simple molecule such as ethane was essentially "free".
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Molecular Structure and Statistical Thermodynamics: Selected Papers of Kenneth S. Pitzer (World Scientific Series on 20th Century Chemistry, Vol 1)
March 1994, World Scientific Publishing Company
Hardcover
in English
9810214391 9789810214395
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Molecular structure and statistical thermodynamics: selected papers of Kenneth S. Pitzer
1993, World Scientific
in English
9810214391 9789810214395
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