| Record ID | marc_columbia/Columbia-extract-20221130-016.mrc:20359453:3451 |
| Source | marc_columbia |
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LEADER: 03451cam a22003374a 4500
001 7577190
005 20221201011857.0
008 090903t20102010flua b 001 0 eng
010 $a 2009034801
020 $a9781420067927 (hardcover : alk. paper)
020 $a1420067923 (hardcover : alk. paper)
024 $a40017457996
035 $a(OCoLC)ocn156818663
035 $a(OCoLC)156818663
035 $a(NNC)7577190
035 $a7577190
040 $aDLC$cDLC$dYDX$dOrLoB-B
050 00 $aQD281.A5$bS27 2010
082 00 $a547/.2$222
100 1 $aSartori, Giovanni,$d1944-
245 10 $aAdvances in Friedel-Crafts acylation reactions :$bcatalytic and green processes /$cGiovanni Sartori and Raimondo Maggi.
260 $aBoca Raton, FL :$bCRC Press,$c[2010], ©2010.
300 $axii, 207 pages :$billustrations ;$c25 cm
336 $atext$btxt$2rdacontent
337 $aunmediated$bn$2rdamedia
504 $aIncludes bibliographical references and index.
505 00 $gCh. 1.$tIntroduction and scope -- $gCh. 2.$tStoichiometric acylations -- $gCh. 3.$tCatalytic homogeneous acylations -- $gCh. 4.$tCatalytic heterogeneous acylations -- $gCh. 5.$tDirect phenol acylation: The Fries rearrangement -- $gCh. 6.$tConcluding remarks-future outlook.
520 1 $a"Used in the production of a wide number of fine chemicals and pharmaceuticals, the Friedel-Crafts acylation reaction represents a synthetic process of great interest to organic chemists of academia and industry. Nearly 40 years since the last major treatise on the topic and reflecting the growing emphasis on green technology, Advances in Friedel-Crafts Acylation Reactions: Catalytic and Green Processes focuses on how to make this reaction more economically and environmentally friendly by using green acylating conditions, thus minimizing the formation of waste and decreasing production costs." "Divided into four parts, the book explores stoichiometric acylations, catalytic homogeneous acylations, catalytic heterogeneous acylations, and phenol acylations. It is structured according to the role played by the catalyst in the activation of reagents as well as in the different modes of regioselectivity encountered in the acylation of arenes, aromatic ethers, and phenols." "Incorporating examples of all acid-catalyzed Friedel-Crafts acylation reactions, the text considers classic Lewis and Bronsted acid types along with more innovative and advanced multicomponent superacid catalysts. These range from rare earth triflates or triflimides and their combination with ionic liquids to metal-promoted zeolites and zeotypes, clays, polymetal oxides, sulfated zirconia, heteropoly acids, and Nafion. The book emphasizes the major industrial applications, providing a critical assessment of the differences, advantages, and disadvantages of homogeneous and heterogeneous catalysis." "Helping readers to better understand the mechanism of the Friedel-Crafts acylation, the examples in the book substantiate the development of more effective catalysts and more selective processes achieved during the last few decades, enabling industry to embark on a safer and more efficient synthesis of aromatic ketones for the manufacture of a wide array of products."--BOOK JACKET.
650 0 $aFriedel-Crafts reaction.$0http://id.loc.gov/authorities/subjects/sh85051977
700 1 $aMaggi, Raimondo.$0http://id.loc.gov/authorities/names/n2009056250
852 00 $boff,sci$hQD281.A5$iS27 2010