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LEADER: 07510cam 2200889Ii 4500
001 ocn967726940
003 OCoLC
005 20220207003523.0
008 170105s1991 enka ob 001 0 eng d
006 m o d
007 cr cnu---unuuu
040 $aUKRSC$beng$erda$epn$cUKRSC$dOCLCO$dOCLCE$dOCLCF$dOCLCQ$dLIP$dYDX$dUKAHL$dEBLCP$dUKMGB$dN$T
015 $aGBB6K1389$2bnb
016 7 $a018135200$2Uk
019 $a644030788$a680075011$a1000428033$a1089329284$a1096729120$a1120877112$a1157078824$a1159414232$a1191753173
020 $a9781788010917$q(electronic bk.)
020 $a1788010914$q(electronic bk.)
020 $z9780851869964$q(print)
020 $z0851869963
035 $a(OCoLC)967726940$z(OCoLC)644030788$z(OCoLC)680075011$z(OCoLC)1000428033$z(OCoLC)1089329284$z(OCoLC)1096729120$z(OCoLC)1120877112$z(OCoLC)1157078824$z(OCoLC)1159414232$z(OCoLC)1191753173
037 $a4827:4679$bRoyal Society of Chemistry$nhttp://www.rsc.org/spr
042 $adlr
050 4 $aQD481$b.G6 1991eb
082 04 $a547.035$222
084 $a35.53$2bcl
100 1 $aGokel, George W.,$d1946-
245 10 $aCrown ethers and cryptands /$cGeorge W. Gokel.
264 1 $a[England] :$bRoyal Society of Chemistry,$c1991.
300 $a1 online resource (xii, 190 pages) :$billustrations (some color)
336 $atext$btxt$2rdacontent
337 $acomputer$bc$2rdamedia
338 $aonline resource$bcr$2rdacarrier
490 1 $aMonographs in supramolecular chemistry
520 $aCrown Ethers and Cryptands introduces the broad and basic principles of crown ether and cryptand chemistry at the advanced undergraduate, graduate and working professional level. The book provides a brief introduction, outlining the history of the field and goes on to cover syntheses, complexation of cations and molecules, complex structures, applications and recent developments. It aims to acquaint readers with the scope and principles of the field, providing a bibliography of reviews and books as reference to further reading and citations of the original literature.
504 $aIncludes bibliographical references (pages 178-185) and index.
588 0 $aPrint version record.
506 $3Use copy$fRestrictions unspecified$2star$5MiAaHDL
533 $aElectronic reproduction.$b[Place of publication not identified] :$cHathiTrust Digital Library,$d2010.$5MiAaHDL
538 $aMaster and use copy. Digital master created according to Benchmark for Faithful Digital Reproductions of Monographs and Serials, Version 1. Digital Library Federation, December 2002.$uhttp://purl.oclc.org/DLF/benchrepro0212$5MiAaHDL
583 1 $adigitized$c2010$hHathiTrust Digital Library$lcommitted to preserve$2pda$5MiAaHDL
505 0 $aCover -- Preface -- Contents -- Dedication -- Chapter 1 -- 1.1 Introduction -- 1.2 Crown Ether Precursor Work -- 1.2.1 Lüttringhaus' Macrocycles -- 1.2.2 Cyclo-oligomerization of Ethylene Oxide -- 1.2.3 The Furan-Acetone Tetramer -- 1.3 Pedersen's Discovery of Crown Ethers -- 1.4 Simmons' In-Out Bicyclic Amines -- 1.5 Lehn's Cryptands -- 1.6 Cram and Carbanions -- 1.7 Classes of Crown Ethers and Cryptands -- 1.8 Naturally Occurring Relatives of Crown Ethers -- 1.9 Nomenclature and its Problems -- 1.10 Toxicity of Crown Ether Compounds -- Chapter 2 -- 2.1 Introduction
505 8 $a2.2 Pedersen's First Crowns -- 2.3 Tbe Etbyleneoxy Structural Unit -- 2.4 The Template Effect -- 2.5 Early Syntheses of Crowns -- 2.5.1 Dicyclohexano-18-crown-6 -- 2.5.2 18-Crown-6 -- 2.5.3 [2.2.2]-Cryptand -- 2.6 Syntheses of Crown Ethers -- 2.6.1 Monomers, Dimers, and Trimers -- 2.6.2 Nucleophiles and Bases -- 2.6.3 Leaving Groups . -- 2.6.4 Solvents -- 2.6.5 High Dilution -- 2.6.6 General Conditions -- 2.7 Incorporation of Aromatic Subunits -- 2.8 Nitrogen-containing Macrocycles -- 2.8.1 Proteetion of Nitrogen -- 2.8.2 Lactam Formation Followed by Reduction
505 8 $a2.8.3 Direct Incorporation of Nitrogen -- 2.8.4 Syntheses of Lariat Ethers -- 2.8.5 Multi-armed Lariat Ethers -- 2.8.6 Heteroaromatic Sub-units -- 2.9 Crown Ethers Containing Sulfur -- 2.10 Syntheses of Cryptands -- 2.11 Spherands, Cavitands, and Carcerands -- 2.12 Summary -- Chapter 3 -- 3.1 Introduction -- 3.2 The Extraction Technique -- 3.3 Homogeneous Cation Binding Constants -- 3.3.1 Techniques for Determining Stability Constants -- 3.3.2 Variables Affecting Homogeneous Stability Constants -- 3.3.3 The Macrocyclic Effect -- 3.3.4 Enthalpy-entropy Compensation
505 8 $a3.3.5 Brief Survey of Cation Complexation Constants -- 3.4 Binding Dynamics -- 3.5 Cation Transport -- 3.6 Complexation of Organic Cations -- 3.6.1 Ammonium Cations -- 3.6.2 Chiral Recognition -- 3.6.3 Arenediazonium Cations -- 3.6.4 Hydronium Cation -- 3.6.5 Co-operative Structures -- 3.6.6 A Polymerie Ionophore -- 3.7 Molecular Complexation -- 3.8 Anions -- Chapter 4 -- 4.1 Introduction -- 4.2 Uncomplexed Crown and Cryptand Ligands -- 4.3 Simple Crown Ether Complexes of Metal Cations -- 4.3.1 Crown Complexes of Cations that Are 'Too Large'
505 8 $a4.3.2 Crown Complexes of Cations that Are 'Too Sm all' -- 4.3.3 Complexes of Functional Crown Ether Derivatives -- 4.3.4 Lariat Ether Complexes -- 4.3.5 Bibracchial Lariat Ether Complexes -- 4.4 Cryptand Complexes -- 4.4.1 Simple Cryptand (Cryptate) Complexes -- 4.4.2 Ditopie Cryptands -- 4.4.3 Inclusion vs. Exclusion Complexes -- 4.5 Crown Ether Complexes of Other Ions and Moleeules -- 4.6 Podand Complexes -- Chapter 5 -- 5.1 Introduction -- 5.2 Solubilization Phenomena -- 5.2.1 Solubilization of Salts -- 5.2.2 Crown Activated Reagents -- 5.3 Cation Deactivation
650 0 $aEthers.
650 0 $aCyclic compounds.
650 7 $aCyclic compounds.$2fast$0(OCoLC)fst00885840
650 7 $aEthers.$2fast$0(OCoLC)fst00915813
650 7 $aÉthers.$2fmesh
650 7 $aChimie organique.$2fmesh
650 17 $aKroonethers.$2gtt
650 7 $aEthers cycliques.$2ram
650 7 $aChimie supramoléculaire.$2ram
650 7 $aChimie physique et théorique.$2ram
650 7 $aÉthers.$2ram
650 7 $aComposés cycliques.$2ram
650 7 $aCryptands.$2ram
650 7 $aÉthers en couronne.$2ram
653 $aPhysical chemistry
653 1 $aEthers
655 4 $aElectronic books.
776 08 $iPrint version:$aGokel, George W., 1946-$tCrown ethers and cryptands.$dRoyal Society of Chemistry, 1991$z0851869963$w(DLC) 91096701$w(OCoLC)24713399
830 0 $aMonographs in supramolecular chemistry.
856 40 $3HathiTrust Digital Library, Limited view (search only)$uhttp://catalog.hathitrust.org/api/volumes/oclc/24713399.html
856 40 $3Royal Society of Chemistry$uhttps://doi.org/10.1039/9781788010917
856 40 $uhttp://imp-primo.hosted.exlibrisgroup.com/openurl/44IMP/44IMP_services_page?u.ignore_date_coverage=true&rft.mms_id=9956068592401591$p5387071170001591
856 40 $uhttp://www.vlebooks.com/vleweb/product/openreader?id=none&isbn=9781788010917
856 40 $uhttp://public.eblib.com/choice/PublicFullRecord.aspx?p=6212978
856 40 $3EBSCOhost$uhttps://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&db=nlabk&AN=2489824
938 $aYBP Library Services$bYANK$n301303872
938 $aAskews and Holts Library Services$bASKH$nAH32066147
938 $aProQuest Ebook Central$bEBLB$nEBL6212978
938 $aEBSCOhost$bEBSC$n2489824
029 1 $aUKMGB$b018135200
994 $aZ0$bP4A
948 $hNO HOLDINGS IN P4A - 623 OTHER HOLDINGS