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LEADER: 03207cam a22003138a 4500
001 011801918-X
005 20090731104133.0
008 080314s2009 nju b 001 0 eng
010 $a 2008012231
020 $a9780470089644 (cloth/cd)
035 0 $aocn213466575
040 $aDLC$cDLC
050 00 $aQD453.3$b.K84 2009
082 00 $a541$222
100 1 $aKuhn, Hans,$d1919-
245 10 $aPrinciples of physical chemistry.
250 $a2nd ed. /$bby Hans Kuhn, Horst-Dieter Försterling, David H. Waldeck.
260 $aHoboken, N.J. :$bJohn Wiley,$cc2009.
300 $axlii, 1032 p.$bill. ;$c26 cm.
504 $aIncludes bibliographical references and index.
505 0 $aWave-particle duality -- Essential aspects of structure and bonding -- Schrödinger equation -- Hydrogen atom -- Atoms and the variational principle -- A quantitative view of chemical bonding -- Bonding described by electron pairs and molecular orbitals -- Molecules with [pi]-electron systems -- Absorption of light -- Emission of light -- Nuclei: particle and wave properties -- Nuclear spin -- Solids and intermolecular forces -- Thermal motion of molecules -- Energy distribution in molecular assemblies -- Work w, heat q, and internal energy U -- Reversible work w[subscript rev], reversible heat q[subscript rev], and Entropy S -- General conditions for spontaneity and its applications to equilibria of ideal gases and dilute solutions -- Formal thermodynamics and its application to phase equilibria -- Real gases -- Real solutions -- Reaction equilibria in aqueous solutions and biosystems -- Chemical reactions in electrochemical cells -- Chemical kinetics -- Transition states and chemical reactions -- Macromolecules -- Organized molecular assemblies -- Supramolecular machines -- Origin of life: matter carrying information.
520 $aPrinciples of Physical Chemistry presents a novel approach to physical chemistry that emphasizes the use of a few fundamental principles to quantitatively describe the nature of molecules and their assemblies. It begins with atoms and molecules, using the electron-in-a-box model to illustrate the essential features of quantum mechanics and why atoms and molecules exist. Thermodynamics is not introduced in the classical manner, considering the first and second law as postulates, but approached by studying assemblies of molecules statistically. The authors proceed to molecular assemblies of increasing complexity, evolving from ideal gases to real gases and solutions, then to macromolecules and supramolecular machines, and ending with the search for the logical conditions and chemical requirements for physicochemical processes leading to life's origin, the emergence of matter that carries information. This text is ideal for both undergraduate and graduate courses in physical chemistry, providing a basis for understanding the nature of chemical processes in biology, chemistry, and engineering.
650 0 $aChemistry, Physical and theoretical.
655 7 $aLehrbuch.$2swd
700 1 $aFörsterling, Horst-Dieter
700 1 $aWaldeck, David Hennessey,$d1956-
700 1 $aWaldeck, David H.$q(David Hennessey),$d1956-
988 $a20090109
906 $0DLC