An edition of Chemical Thermodynamics
(2013)
Chemical Thermodynamics
by Leo Lue
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This study guide deals with the application of thermodynamics to the description of the properties of materials. It covers the qualitative behavior of single and multicomponent mixtures, including vapor-liquid, liquid-liquid, and solid-liquid phase equilibria.
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Publish Date
2013
Publisher
Bookboon.com
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Book Details
Table of Contents
Obsah
Introduction
Basic concepts
Brief review of thermodynamics
The fundamental equation of thermodynamics
The calculus of thermodynamics
Open systems
Legendre transforms and free energies
Single component systems
General phase behavior
Conditions for phase equilibrium
The Clapeyron equation
Multicomponent systems
Thermodynamics of multicomponent systems
Binary mixtures
Ternary mixtures
The ideal solution model
Definition of the ideal solution model
Derivation of Raoult’s law
Partial molar properties
Definition
Relationship between total properties and partial molar properties
Properties changes on mixing
Graphical representation for binary systems
Nonideal solutions
Deviations from Raoult’s law and the activity coefficient
Modified Raoult’s law
Empirical activity coefficient models
The Gibbs-Duhem equation
Azeotropic systems
Stability
Introduction
Liquid-liquid equilibrium
Solid-liquid equilibrium
Introduction
Phase behavior
Conditions for equilibrium
Gas solubility and Henry’s law
Henry’s law
Activity coefficients
Equations of state
The principle of corresponding states
The van der Waals equation and cubic equations of state
Equations of state for mixtures
Thermodynamics from equations of state
The residual Helmholtz free energy
Fugacity
Vapor-liquid equilibrium with a non-ideal vapor phase
Chemical reaction equilibria
Conditions for equilibrium
The phase rule for chemically reacting systems
Gas phase reactions
The standard Gibbs free energy of formation
The influence of temperature
Liquid phase reactions
ID Numbers
Links outside Open Library
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History
- Created September 2, 2015
- 4 revisions
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| August 22, 2020 | Edited by ISBNbot2 | normalize ISBN |
| September 2, 2015 | Edited by Alice Kirk | Edited without comment. |
| September 2, 2015 | Edited by Alice Kirk | Added new cover |
| September 2, 2015 | Created by Alice Kirk | Added new book. |